Mercury/Phosphorus Effects

 

 

 Navigation

What effects do chemicals in CFLs have on the environment?

 

Home

 

Mercury

Mercury is a highly toxic chemical.

Its most toxic forms include mercury vapour and methyl-mercury and both are found in CFLs.

When it enters the environment it does not decompose or disappear over time because it is an elemental (pure) substance.

This means it will continue to build up over time in the environment, getting to dangerous levels because it is virtually impossible to remove.

Mercury is harmful to any living thing as it damages parts of the body on a cellular level and stop the body working properly.

Humans can have mercury enter their bodies a number of ways, such as breathing in its vapour or drinking water polluted with mercury.

The most common way mercury enters a human’s body is because people eat fish from a waterway contaminated with mercury.
Because humans are at the top of the food chain this mercury is in higher quantities (the amounts of mercury build up as you go up the food chain).

Mercury affects aquatic life because it can seep through ground and into water ways, especially if a landfill it situated close to a waterway.

Aquatic life, living in either fresh or salt water polluted with mercury, is usually smaller than regular organisms of that species, and will probably have physical deformities, issues with reproduction, and a shorter life time.

All types of aquatic life are affected by mercury including native New Zealand fish species and marine organisms.

Mercury accumulates in the bodies of small fish because it is absorbed by a normal process into their cells.

This mercury stays in their bodies and is passed into the body of anything that eats them.

Therefore, the higher up the food chain, the higher the quantities of mercury.

Mercury affects the central nervous system and the brain, in humans, and is a real danger to younger people as it can effect their development.

A pregnant woman who is exposed to mercury can pass it, and its damaging effects, on to her unborn baby. This may cause birth defects.

The problem with mercury in CFLs is that it is released into the environment when the bulb breaks or is disposed of incorrectly.

Mercury vapour can be breathed in from a broken bulb or if the bulb breaks in a landfill the mercury inside the bulb ends up in the environment.

The amount of mercury contained in one bulb is not seen as much of a problem because it is so small (less than is used daily in a dentist surgery or than is emitted during the production of fossil fuel power).

But when a number of bulbs break or are disposed of incorrectly after failure, the mercury from all these bulbs begins to build up in the environment to potentially dangerous levels.

This is why bulbs which fail must be sent to a hazardous waste recycling centre. There is only one company able to recycle CFLs, throughout New Zealand, and it is expensive to use this service if you are only recycling one bulb.

However some stores are willing to take back failed bulbs and store them until they have enough to recycle which is more economical.

Another point to note is that some bulbs claim they use amalgam instead of mercury in the bulb tube however amalgam is a substance which contains mercury and studies have shown that the mercury in amalgam can and does escape in the form of mercury vapour meaning that amalgam can be just as dangerous. 

It has also been argued using incandescent bulbs releases more mercury into the environment than CFLs because they require more power.

If this power is coming from fossil fuels this claim is justified because fossil fuel power does emit mercury into the environment, (more than is contained in a single CFL) however this claim is irrelevant in areas, like New Zealand, which uses alternative energy sources, like such as hydro, wind and solar power. 

For more information on the affect of mercury see the links on the further reading page.

 

Phosphorus

 

Phosphorous is an elemental substance which is used in small quantities in CFLs with mercury to make the ultra-violet light (produced by the mercury) visible.

There are a number of different forms of phosphorus and each can have reaction with certain environmental conditions to become another type or compound.

Many forms of phosphorus and its naturally occurring organic compounds are toxic and therefore hazardous to the environment.

The most dangerous form of phosphorus is white phosphorus.

White phosphorus causes can burn your skin.

It can also spontaneously combust with air.

If Yellow phosphorus (a mix of red and white phosphorus) is ingested it causes severe liver problems

Fluorophosphate esters are highly toxic to the environment and poison living things.

Red Phosphorus gives off highly toxic fumes.

Phosphorus is not as dangerous as mercury because it is more easily removed from the environment than mercury and has forms which are not dangerous.

For more information about the affects of phosphorus see the links on the further reading page.


Plastics

 

If a CFL overheats and melts or fails in another way which causes its casing to melt toxic chemicals are released into the environment because of the decomposition of the plastic.

For more information on the effects of chemicals given off by melting plastic see the links on the further reading page.



 

Better Bulbs?

Light/Cost Efficiency

Suitability

Retail Prices

Recycle-ability

Radio Interference

Box Claims

“The Science Behind It”

Mercury/Phosphor Effects

Glossary

Further Reading